National Green Tribunal
Rajasekar Shambu vs The Chairman Karnataka State Pollution ... on 9 May, 2022
Bench: K Ramakrishnan, K. Satyagopal
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3
JOINT INSPECTION REPORT
Name of the Industry Inspected: M/S Syntho Chirals Private Limited, Kolhar Industrial
Area, Bidar.
Name of the Inspecting Officers:
1. Shri S Madhusudhan Senior Environmental Officer, Zonal Office Kalburgi
2. Shri Gopalkrishna B Sanatangi Environmental Officer KSPCB Bidar.
Reference: The Board direction issued vide memo dated: 05.04.2022
Date of Inspection 12.04.2022, and monitoring carried on
11.04.2022
Consent status Water Act 1974 Air Act 1981
AW-313104 AW-313104
30.06.2023 30.06.2023
Products manufactured As per CFO Actual Manufactured
Sr | Product Name Sr | Product Name
1 | Acylovir 1 | Acylovir
2 Alendronate 2 Alendronate
Sodium Sodium
betamethasone betamethasone
3 : ; 3 : :
Di-propinate Di-propinate
Betamethasone Betamethasone
4 | Sodium 4 | Sodium
Phosphate Phosphate
5 Betamethasone 6 Betamethasone
Valerate . Valerate
6 clerrythomycin 6 clerrythomycin
tests only tests only
Clobetasol Clobetasol
7 | Nate-17- 7 | Nate-17-
Propinate Propinate
Dexamethasone Dexamethasone
8 | Sodium 8 | Sodium
Phosphate Phosphate
9 | Irate Canozole 9 | Irate Canozole
10 | Ketacenazole 10 | Ketacenazole
11 | P-Panthenol 11 | P-Panthenol
12 | phenylene 12 | phenylene
Page 56 of 110
4
propane amino propane amino
hypo chloride- hypo chloride-
salts only salts only
13 Pyrazine B Pyrazine
Amide Amide
Triazole Triazole
ue Mesylate 4 Mesylate
triazole triazole
er
| 15 | piperzine-test 15 | piperzine-test
OC
scale only scale only
ET OORT et
HWM Status Valid upto 30/06/2023
e
eee ee
WATER POLLUTION CONTROL STATUS
Source of water: Open Well
SS
Quantity of water consumption as per Consent: 7 KLD
Actual water consumed for different purposes: 7 KLD
ee
Quantity of effluent generation from different sources as per CFO;
Sources of generation Quantity Mode of treatment and disposal
Domestic 3
Process Z Feed tank to MEE system and
MEE system followed by
agitator thin film drier (ATFD)
Washings Feed tank to MEE system and
MEE system followed by
agitator thin film drier (ATFD)
Boiler blow down MEE
RO Rejects MEE
Page 57 of 110
Tt NSPE ED
5
RS EBT
5. Details of effluent treatment plant
EEE
STP units
f
b. MEE 20 KLD
c. Condensate treatment plant
d . Closed loop system for solvents and raw material handling.
Ostet EE Se tae ae ee Eee eS Ty
AIR POLLUTION CONTROL STATUS
Slno_ | Air Pollution source Air pollution Chimney _ Monitoring
control height above' | facility
GH EAL Ringe RetANC
equipment ground level
provided
1 Process emissions Scrubbers 15 feet above provided
from GLR, No of roof level
GLRs
2 MEE
S ATFD Condenser NA NA
4 Boiler with capacity 1.5 Ton 90 feet Provided
: D G sets with capacity | 250 15 feet
SOLID WASTE MANAGEMENT At
1. HAZARDOUS WASTE
SL.NO | SOURCE OF QUANTITY MODE OF PRESENT
GENERATION OF STORAGE STOCK IN
GENERATION | AND THE
PER DAY DISPOSAL STORAGE
YARD
1 Process residue 30 KG Packed in 1000 Kgs
double lined
Poly bags &
Stored at
Designated
area and
disposed to
Authorised
TSDF
2 Activated carbon 2Kg Packed in
sludge double lined
Page 58 of 110
6
Mt'
Poly bags &
Stored at
beta rg © CORREA TE SEN
Designated
area
3 MEE salts 200 KG Packed in 2000 Kgs
Ee ENT tote Sakeinente aoe Sopatie scutes
double lined
Poly bags &
Stored at
Designated
area and
disposed to
Authorised
TSDF
ae eee eae ent Te re Te BN ES ee eed ee EOE SN LTE Oe TCE
4 DISCARDED 10 numbers per Handed over
CONTAINERS month to authorized
recycler
. OTHER WASTE
SL.NO | SOURCE OF QUANTITY MODE OF PRESENT
GENERATION OF STORAGE STOCK IN
GENERATION AND THE
PER DAY DISPOSAL STORAGE
YARD
1 DOMESTIC
Oe earte ce Cs ee ae eee ae Pee
eee
2 OFFICE 10 Kgs Per Disposed to
STATIONARIES Month Waste paper
Vendor
xT
3 E WASTE ~"t
BE oe
4 BOILER ASH 30 -- 40 Kgs per Stored in 1 Ton
Day Ash Shed
and
disposed to
Brick
Manufacture
5 SCRAPS IRON Nil
AND STEEL
"A
Page 59 of 110
7
COMPLIANCE TO THE OBSERVATIONS OF THE JOINT COMMITTEE
VISIT DATED 27.11.2019
SIN | Observations | Compliance
Oo
} The Unit has | They are having valid consent and Hazardous Waste
displayed the | Authorization and also displayed at the entrance of the main
Consent and gate.
Hazardous »
waste 'Prt Ltd,
authorization ee
i cin
conditions at
the entrance of
the Unit, as
per the
direction of
the Hon'ble
Supreme
Court Order in
W.P No (C)
657/1995.
The unit has Authorization No: 322967
valid consent Valid up to 30/06/2023
and Hazardous
waste
authorization.
The source of They have provided the water flow meter at open Well
water supply
is Own open Obtained NOC From the Karnataka Ground Water Authority.
well and not Attached
installed flow
meter and
water
consumption
record is not
available. The
unit has not
obtained NOC
from the
Karnataka
Ground Water
Authority
(KGWA) for
Page 60 of 110
8
usage of
Ground water
for industry
use.
inccuracy. 5 1m
"Time: 12-04-2022 15:18
= 3 Chirels open
The raw As Civil repair and maintenance work was going in warehouse
materials are They have stored the goods in shed with proper precaution as
stored in shed. per the norms of PCB.
The closed They don't have closed system for Solvent Handling
loop system
for solvent
handling is
under
commissionin
g..
During During the inspection it was noticed that, the plant was under
inspection operation.
there was no
production and
informed that
the plant was
under
maintenance
shut down.
The unit has They have installed Flow meter and cameras to MEE and also
installed flow installed the OCEMS and same Connected to CPCB/KSPCB on
meter and 11.12.2019
camera to
MEE, but
OCEMS is not
yet connected
to
CPCB/KSPCB
Page 61 of 110
9
The unit has They are maintaining the records of the
20 KLD ETP, MEE.
the low TDS
and High TDS
effluent are
combined
treated with
neutralization
followed by
Multiple
Effect
Evaporator
(MEE) and
Agitated thin
Film Drier
(ATED). The
salt generated
is disposed to
common
TSDF. The
MEE
Condensate is
used as Boiler
feed. The Unit
informed that
MEE is not
operated
continuously
and only four
times ina
month. There
is need to
maintain flow
records. Since
the plant is
under
maintenance
shutdown, the
committee
could not
carryout
sampling to
assess the
Page 62 of 110
10
performance
of MEE.
The unit They have replaced the Loose pipe lines with permanent Lines
transfers the ue cp wf
effluent from
collection tank
to the MEE by
the loose pipe
lines, need to
be replaced
with
permanent
line.
The Unit has Reactors are not in operation as Production Block is under
erected the construction the Reactors are kept under Safe condition as per
process reactor
adjacent to the
MEE, the
same need to
be removed
and shifted to
other place.
Elevat , ae
fe aS mi
CCU! om
10 The unit has They are disposing the residues to TSDF.
stored off They have Constructed Separate Block for the storage of H.W
specification with spillage collection Pits
products/proce
ss residues etc.
in large
quantity, the
unit shall
dispose the
same as per
the HWM
Authorization
immediately.
The unit needs
to develop esis rag Sicatsiaieaicitiotits,
Page 63 of 110
11
adequate
storage area of
HW with
spillage
collection pits.
11 The unit is not They have taken over the sick unit and improvements is under
having storm progress.
water
management
system,
collection and
treatment of
the same.
12 There is an The sample of well water is collected for analysis. Report is
existing open awaited.
well in the
plant
premises, open
well sample
was collected
for analysis
(GW6), the
analysis
results are
discussed at
section 5 iii.
The well water
was not
conforming
w.r.t COD,
Total
Hardness and
Ammonia.
MONITORING
The sample of condensate of MEE is collected for analysis..
The sample of open well/tube well collected for analysis.
i
The sample of ambient air quality is conducted.
The emissions from scrubber outlet are collected for testing acid mist concentration.
Page 64 of 110
12
The above samples are submitted to KSPCB Laboratory for analysis purpose. The report is
awaited.
Apart from the above, the following important observations were made:
a. There is no discharge/bypass of effluent to outside the premises.
b. The said unit has adopted Zero Liquid discharge facility.
c. The Non compliances observed during the Joint committee visit on 26/11/2019 has been
complied with except that_the Industry has not adopted treatment for condensate before
using for cooling tower, not provided storm water management and closed loop system
for solvent handling.
The Industry authorities have sought time of 3 months (three months) to adopt treatment
for condensate, to provide storm water management measures and closed loop system for
solvent handling.
ENVIRON
KSPCB, BIDAR
Oan--
SENIOR ENVIRONMENTAL OFFICER
KSPCB, ZONAL OFFICE, KALABURGI
Page 65 of 110
13
JOINT INSPECTION REPORT
VERE TIS Or Td ap TITTY
Name of the Industry Inspected: M/S Suryakala Laboratories Pvt Ltd, Kolhar Industrial
Area Bidar a
FEIT TS
Name of the Inspecting Officers:
TEE
1. Shri S Madhusudhan Senior Environmental Officer, Zonal Office Kalburgi
ee Re
2. Shri Gopalkrishna B Sanatangi Environmental Officer KSPCB Bidar.
Tr 8 et aaa aie a ee ee ee
Reference: The Board direction issued vide memo dated: 05.04.2022
Date of Inspection 07.04.2022, 13.04.2022
monitoring on 12.04.2022
Consent status Water Act 1974 | Air Act 1981
AW-104346 AW-104346
: 30/06/2022 30/06/2022
. Products manufactured As per CFO Actual Manufactured
CFO copy We are manufacturing
enclosed in products as per CFO.
Annexure-1
HWM Status ' 30/06/2021. Applied for Renewal / process.
WATER POLLUTION CONTROL STATUS
1. Source of water:
2. Quantity of water consumption as per Consent:
3. Actual water consumed for different purposes:
4. Quantity of effluent generation from different sources as per CFO;
Sources of generation Quantity Mode of treatment and
disposal
Domestic 4KLD SEPTIC TANK
Process 29 KLD MEE
Washings 1 KLD MEE
Boiler blow down 1 KLD MEE
ae
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14
RO Rejects 1 KLD MEE
If any others 1KLD MEE
5. Details of effluent treatment plant
a. STP units : 4 KLD
hy
b. MEE : 30KLD
RNS IN eer
c. Condensate treatment plan : Not provided. The condensate is directly used for
cooling tower Mt
Rptans RISE fo, Fa
SR as tere REE
AIR POLLUTION CONTROL STATUS
é Sl.no | Air Pollution source Air pollution Chimney Monitoring
i
e control height above facility
i
equipment ground level
provided
1 Process emissions 11 NO's GIRs 3- stage Circulation
from GLR, No of available scrubbing of lye water
GLRs system and
provided with | monitoring
ta See
blower height: | the PH of
PUREE a wane eee
60 ft. the
- scrubber
solution
2 MEE Scrubber NA NA
3 ATFD 24 kid capacity | Chimney Proposed
hes ns eke ee
ATFD is height is 40 ft. | port hole
Stat AG UdeS whee ere fee
provided. with condenser
- Boiler with capacity 4Ton&2Ton | Chimney Port hole
Boilers are height is 103 ft. | provided
available.
5 D G sets with capacity | 250 kva&500 | Chimney NA
kva height is 6 ft.
SOLID WASTE MANAGEMENT
1, HAZARDOUS WASTE Ae
SL.NO | SOURCE OF QUANTITY MODE OF PRESENT
GENERATION OF STORAGE STOCK IN
GENERATION | AND THE
PER DAY DISPOSAL STORAGE
Page 67 of 110
15
M
"7
YARD
1 Process residue 600 kgs Cement Nil
aT ene te ee GEOR © Pe TRA Rete ao ep ctrr SRT tt tnectaes reise py
recliners
2 Activated carbon 50 kgs TSDF 100 kgs
sludge
3 MEE salts 1500 kgs TSDF 400 kgs
4 DISCARDED 50 kgs Authorized 10
CONTAINERS recycliers
2 IF ANY OTHER
2. OTHER WASTE
PR Ne Sekt a mE RT Po ty A
SL.NO | SOURCE OF QUANTITY | MODEOF' | PRESENT
GENERATION OF STORAGE | STOCK IN
GENERATION | AND THE
PER DAY DISPOSAL | STORAGE
YARD
1 DOMESTIC - - -
2 OFFICE 2 = 3
STATIONARIES
3 E WASTE 5 kgs Exchange Nil
4 BOILER ASH 1 Ton Send to red | 2 tons
brick
industries
and farmers
5 SCRAPS IRON - - oe
AND STEEL
COMPLIANCE TO THE OBSERVATIONS OF THE JOINT COMMITTEE VISIT
DATED 27.11.2019
SLN_ | Observations Compliance
0
"a
Page 68 of 110
16
The Unit has YES, the unit has displayed the Consent and Hazardous waste
displayed the authorization conditions at the entrance of the unit.
Consent and
Hazardous
waste
authorization
conditions at
the entrance of
the Unit, as per
the direction of
the Hon' ble
Supreme Court
Order in W.P
No(C)
657/1995.
The unit has Validity expired, Applied under process.
valid consent
and Hazardous
waste
authorization.
The source of The source of water is from outside tankers. Flow meters are
water supply is installed at the input and various
open well Discharge points in the unit and regularly recording the
located within consumption of the same.
the premises
and tankers,
not installed
flow meter for
water
consumption
and record is
not available.
The Unit has
not obtained
NOC from the
Karnataka
Ground Water
Authority
(KGWA) for
Page 69 of 110
17
usage of
Ground water
for industry
use.
The unit is not Not provided, However the industry has provided pipe for old
having closed solvent tank having scrubber. They are proposing to shift all
loop system solvent tanks at one place.
for solvent
handling to
minimize the
solvent loss.
The Unit has
installed
OCEMs and
connected to
CPCB/KSPCB
. The OCEMS
is found
working.
Time: 12-04-2022 15:35 '
Note: Suryakala Li
Page 70 of 110
18
The unit has The MEE & ATFD is in working condition.MEE tubes are
30 KLD ETP, changed to increase the performance and also new ATFD with
the low TDS capacity of 1 kl/hr is installed. To ascertain the claim of the
and High TDS industry in respect of the tolerance limit of condensate the
effluent are sample of the same is collected for analysis purpose. Report is
combined awaited.
treated with The applicant is of the opinion that treatment for the condensate
neutralization is not required since the tolerance limit is within norms,
followed with however this can be only known after the receipt of analysis
stripper, report.
Multiple Effect
Evaporator
(MEE) and
Agitated thin
Film Drier
(ATFD). The
salt generated
is disposed to
common
TSDF. The
MEE
Condensate is
used as Boiler
feed. The
analysis results
of effluent
samples reveal
that, the MEE
condensate is
reported with
high
concentration
of COD and
alkaline PH,
which
indicates that
poor.
Performance
of MEE
condenser and
condensate
generated is
not suitable for
recycling as
cooling tower,
make up water.
Page 71 of 110
19
The unit has MEE salts are disposed at regular intervals. The spillage
storage of collection pit is also provided at the Hazardous waste storage
large quantity area.
of process
residue and
MEE salts
about 20 Tons,
the same is
stored in
unscientific
haphazardly in
HWM storage
area. Due to
huge storage,
there is
generation of
leachate,
which is
coming out of
storage area.
The unit shall
immediately
dispose the
same to the
authorized
agency as per
HW
authorization
| Accuracy: 27.6
and shall not 'Time: 12-04-2022 15:37
Note: Suryakala Laboratories pvt itd Hazardous waste storage spillage collection pit photo S
accumulate
large quantity
of solid waste
and dispose the
same at regular
frequency.
There is no
spillage
collection pit
existing in
HWM storage
area.
Page 72 of 110
20
7 Coal ash is stored in separate room and the same is disposed to
Coal is used as | brick industries at regular intervals.
fuel in Boiler,
the ash
generated from
the Boilers,
ash lumps and
fine ash shall
be stored
separately in
bags to avoid
fugitive
emissions.
The unit is not
having storm
water
management
system,
collection and
treatment of
the same.
MONITORING
The sample of condensate from is collected for analysis..
=
The sample of ambient air quality is conducted. wn The emission from scrubber outlet is collected for testing acid mist concentration. The above samples are submitted to KSPCB Laboratory for analysis purpose. The report is awaited.
Page 73 of 110 21The above samples are submitted to KSPCB Laboratory for analysis purpose. The report is awaited.
Apart from the above, the following important observations were made:
a. There is no discharge/bypass of effluent to outside the premises. b. The said unit has adopted Zero Liquid discharge facility. c. The Non compliances observed during the Joint committee visit on 26/11/2019 has been complied with except that_the Industry has not adopted treatment for condensate before using for cooling tower, not provided storm water management and closed loop system for solvent handling.
The Industry authorities have sought time of3 months (three months) to adopt treatment for condensate, to provide storm water management measures and closed loop system for solvent handling.
YTAL OFFICER KSPCB, BIDAR oe SENIOR ENVIRONMENTAL OFFICER KSPCB, ZONAL OFFICE, KALABURGI Page 74 of 110 22 JOINT INSPECTION REPORT Name of the Industry Inspected: M/S Sri Lakshmi Chemicals, Kolhar Industrial Area Bidar Name of the Inspecting Officers:
W ON TMATE
1. Shri S Madhusudhan Senior Environmental Officer, Zonal Office Kalburgi
2. Shri Gopalkrishna B Sanatangi Environmental Officer KSPCB Bidar.
HET E EE ONIN Reference: The Board direction. issued vide memo dated: 05.04.2022 ees TN TUTE Date of Inspection 07.04.2022 ,13.04.2022, oe a ea Monitoring carried on 11.04.2022 Gees eT Consent status Water Act 1974 Air Act 1981 ee to Ae eT Nae Nee Valid upto Valid upto Se 30.06.2022 30.06.2022 Products manufactured As per CFO Actual Manufactured TOTS ON IPCA(Iso Propyl | IPCA(Iso Propyl Ree Chloro Acetate) Chloro Acetate) PRN HWM Status Valid upto 25.09.2025 WATER POLLUTION CONTROL STATUS Source of water: Third Party Water supplier by Water Tankers Daily Quantity of water consumption as per Consent:5.0KLD See Actual water consumed for different purposes:3.5KLD Quantity of effluent generation from different sources as per CFO;0.500MT Sources of generation Quantity Mode of treatment and disposal Domestic 1.500 Treated in Septic tank and Soak pit Process 2.000 The trade effluent 0.30KLD is being pre treated and then further treated in Multiple Effect Evaporator followed by Agitated Thin s oy Page 75 of 110 23 oes Trent becca e Film Drier. The MEE/ATFD condensate is used for cooling tower #.
%:
x makeup to achieve zero + pe liquid discharge. The salts IES eee ene tog OR eT EAT ET Eee SSR Sond pe Bee tt"
generated at MEE/ATFD is disposed as hazardous waste in authorized TSDF.
Washings 0.30 MEE"
Boiler blow down 0.30 Neutralized and used for
Gardening.
RO Rejects Nil NA
NN TT wn OL
If any others Nil NA
eee
ee
. Details of effluent treatment plant a. STP units : Nil b . MEE: 30 KLD c. Condensate treatment plant: Nil d. Closed loop system for solvents and raw material handling: Work under progress. At present using vaccum suction from the 200 liters drums.
"ML
AIR POLLUTION CONTROL STATUS
Sl. | Air Pollution source Air pollution Chimney Monitoring facility
no control equipment | height above
provided ground level
1 | Process emissions from | GLR's 8, having 4 | 20m Port hole provided GLR, No of GLRs scrubbers 2 | MEE 30KLD NA NA 3 | ATFD 20m NA NA 4 | Boiler with capacity 125TF8 30m Port hole provided 5 | D Gsets with capacity | 62.5KVA 3m NA SOLID WASTE MANAGEMENT :
1. HAZARDOUS WASTE SL.NO SOURCE OF QUANTITY MODE OF PRESENT STOCK IN GENERATION OF STORAGE THE STORAGE Page 76 of 110 24 s sh ENO GENERATION | AND YARD FERS PS Se PER DAY DISPOSAL 1 Process residue 15 kgs Authorised Nil EERE TSDF 2 Activated carbon NIL Nil Nil IE sludge ES SC 3 MEE salts 15kgs Authorised Nil e cit ul Se he te ey eee EEE TSDF 4 DISCARDED 20 nos Drum 20 numbers CONTAINERS purchaser 5 IF ANY OTHER Nil Nil Nil
2. OTHER WASTE « pe hrur POE SL. | SOURCE OF QUANTITY OF | MODE OF PRESENT STOCK IN NO | GENERATION GENERATION | STORAGE THE STORAGE YARD PER DAY AND DISPOSAL 1 DOMESTIC Nil Nil Nil 2 OFFICE Nil Nil Nil STATIONARIES 3 E WASTE Nil Nil Nil 4 BOILER ASH 50kg Sold to Brick Nil Industry 3 SCRAPS IRON AND Skg Sold to Iron Nil STEEL Scrap Purchaser ML al j COMPLIANCE TO THE OBSERVATIONS OF THE JOINT COMMITTEE VISIT DATED 27.11.2019 Si. Observations Compliance No s mt Page 77 of 110 25 The Unit has | Updating Weekly once displayed the Consent and Hazardous waste authorization conditions at the entrance of the Unit, as per the direction of the Hon'ble Supreme Court Order in W.P No (C) 657/1995.
The unit is not Consent Valid up to 30.06.2022 having valid Hazardous Waste Authorization Valid up to 25.09.2025. Copies consent and | enclosed. Hazardous waste authorization.
The unit is not in operation, applied for renewal of consent.
The source of | Third party water suppliers by Tankers Daily. water supply is | Procurement, Storage and consumption details maintained in by tankers not | separate register. Copies enclosed. having own source. There is no water consumption record available.
The unit is not Closed loop system for solvents work is under process. having closed Meanwhile we are using dedicated pipes and drums for handling loop handling of solvents. system for solvent. There two solvent storage tanks exists.Page 78 of 110 26
The unit has | Arranged the spillage collection pit for Hazardous Waste storage provided room. Segregated and dedicated area allotted for solvent drums.
ex hazardous waste | = ------
storage area found with process residue storages and storage area is not spillage collection pit.
The used solvent drums are stored in open place.
The unit is use Coal ash stored in separate shed and disposed to Brick industry coal as fuel for purchaser. boiler and ashes generated are not properly handled.
The source of Third party water suppliers by Tankers Daily. water supply is Procurement, Storage and consumption details maintained in own open well separate register. Copies enclosed. and not installed flow meter and water consumption record is not available. The unit has not obtained NOC from the Karnataka Ground Water Page 79 of 110 27 Authority (KGWA) for usage of Ground | water for industry use.
The raw Yes
materials are
storedin shed. |
The closed loop |
system for
solvent handling |
is under
commissioning.
During | Yes
inspection there
was no |
production and
informed that
the plant was
under
maintenance
shut down.
10 The unit has OCEMS is connected and data push up to KSPCB and CPCB
installed flow
meter and
camera to MEE,
but OCEMS is
not yet
connected to
CPCB/KSPCB
11 The unit isnot | Storm Water Collection point arranged and treated through
|
having storm af
MEE.
Page 80 of 110
28
water
management
system,
collection and
treatment of the
same.
MONITORING
The sample of condensate from MEE will be collected for analysis..
The sample of open well/tube well will be collected for analysis. eet The sample of ambient air quality will be conducted. The emission from scrubber outlet will be collected for testing acid mist concentration.
The above samples are submitted to KSPCB Laboratory for analysis purpose. The report is awaited.
Apart from the above, the following important observations were made:
a. There is no discharge/bypass of effluent to outside the premises. b. The said unit has adopted Zero Liquid discharge facility. c. The Non compliances observed during the Joint committee visit on------ has been complied with except that the Industry has not adopted treatment for condensate before using for cooling tower _and closed loop system for solvent handling.
The Industry authorities have requested 1 month (one month) time period to adopt treatment for condensate and closed loop system for solvent handling.
The said bulk drug unit has complied with the conditions stipulated in the consent for operation issued by the Board.
ENVIRON AL OFFICER
KSPCB, BIDAR
SENIOR ENVIRONMENTAL OFFICER
KSPCB, ZONAL OFFICE, KALABURGI
Page 81 of 110
29
"3 JOINT INSPECTION REPORT
iin ait inate di Lat ek Sa ak ee Name of the Industry Inspected: M/S Chandra Life Sciences Pvt Ltd Kolhar Industrial Area Bidar : Name of the Inspecting Officers:
1. Shri S Madhusudhan Senior Environmental Officer, Zonal Office Kalburgi E 2. Shri Gopalkrishna B Sanatangi Environmental Officer KSPCB Bidar.
: Reference: The Board direction issued vide memo dated: 05.04.2022 Date of Inspection 07.04.2022 13.04.2022 ee Monitoring on 13.04.2022 Consent status Water Act 1974 Air Act 1981 Active - AW-323366 | Active - AW-323366 Valid up to Valid up to 30.06.2023 30.06.2023 Products manufactured AsperCFO * Average Actual Qty / Month Manufactured (+)-2-(chlorophenyl)N-[2-[2 thienyl) 6.0 ~5.0MT : ethyl] glycine methylester hydrochloride(coupled amine) : (-) p-Chloro benzhydryl piperazine 0.5 0 2-[4[(4-Chloro phenyl)pheny1 0:5 0 methyl} piperzineyll]ethoxy]aceticacid (LCZ VII) Tartaric salt of Clopidogrel (CPA II) 6.0 5 MT Clopidogrel bi sulphate 6.0 0.25 MT 2-(2-Thienyl) Ethyl-4-Methyl Benzene 6.0 00 Sulfonate (CP B mass) CP I 6.0 00 DFTA I 18.0 a 3.50 MT DFTA II 18.0 2.17 MT Donepezile intermediate 1.0 NA Fluconazole 18.0 0.80 MT Itraconazole 3.0 00 Itraconazole and its intermediates 3.0 00 Leevocetorizine Dihydrochloride 0.5 0.02 MT Quetiapine Fumarate IP/EP and its 3.0 00 intermediates Tartaric salt of Levocetrizine(LC II) 0.5 00 Page 82 of 110 30 i i i 5 Voricanazole and its intermediates 1.0 [ 00 t HWM Status f Valid up to 30.06.2023 TONS: at 2 RMT EE eg WATER POLLUTION CONTROL STATUS Source of water:Openwell ee eee Quantity of water consumption as per Consent:53 KL Ree Actual water consumed for different purposes: Avg 48KL - Pe ROLE DOE en Quantity of effluent generation from different sources as per CFO!{9KL Mode of treatment and Sources of generation Quantity (KL) disposal Se net lire fee ee FEN Domestic 6.5 Sock Pit pet Chew aes sae Process 10 MEE Washings 1 MEE Boiler blow down 2. Used For Coal Ash Quenching RO Rejects 3 MEE If any others NA NA Details of effluent treatment plant a. STP units NA b. MEE YES c. Condensate treatment plant -- MEE condensate is sent for cooling tower make up d. Closed loop system for solvents and raw material handling --- YES AIR POLLUTION CONTROL STATUS Sl. No | Air Pollution source Air pollution Chimney Monitoring facility control height above Page 83 of 110 eee Ne ee ae nets OE eT eee eee eae nee EPs 31 MM equipment | ground level provided (Meters) 1 Process emissions MSV LABS from GLR, No of SCRUBBER- 9 AGL (Monthly) GLRs 11 NO's 2 No's 2 MEE NA NA MSV LABS ee a (Monthly) ses gt Se SE EE ee Pere cee ee Ee Se a Vee ee Pe eee 3 ATFD NA NA NA 4 Boiler with capacity 2T &1T 22 METERS MSV LABS (Monthly) 5 D G sets with capacity | 330 KVA 6 AGL at MSV LABS (Monthly) SOLID WASTE MANAGEMENT LE
1. HAZARDOUS WASTE SL.NO | SOURCE OF QUANTITY OF | MODE OF PRESENT GENERATION GENERATION | STORAGE AND | STOCK IN PER DAY DISPOSAL THE STORAGE YARD 1 Process Residue 50 to 75 Kgs / Stored in secured | 5.60 MT Day manner 2 Activated Carbon 2to5Kgs/Day | Stored in Secured | 200 Kgs.
Sludge manner *'
3 MEE Salts 300 to 500 Kgs/ | Stored in secured | 3.779 MT
Day , manner. Handed
over to authorized
TSDF (Mother
Earth)
4 Discarded Containers | 5 Nos. / Day Re-used in the Nil
plant.
5 IF ANY OTHER Not Applicable | Not Applicable Not
Applicable
2. OTHER WASTE
SL.NO | SOURCE OF QUANTITY |MODEOF | PRESENT
GENERATION OF STORAGE | STOCK IN
Page 84 of 110
32
GENERATION AND THE
PERDAY | DISPOSAL | STORAGE
YARD
1 DOMESTIC 4 Kgs/Day | Used in Used in
| Boiler Boiler
2 OFFICE 1Kg/Day | Used in Used in
STATIONARIES _ Boiler Boiler
3 E WASTE Nil "Nil Nil
4 BOILER ASH 100 Kgs/Day Brick Brick
| Manufacturer | Manufacturer 5 SCRAPS IRON 1 to3 Kgs/Day | Stored in 200 Kgs.
AND STEEL Scrap Yard COMPLIANCE TO THE OBSERVATIONS OF THE JOINT COMMITTEE VISIT DATED 27.11.2019 SLNo | Observations Compliance 1 The Unit has displayed the Consent and Yes Hazardous waste authorization conditions at the entrance of the Unit, as per the direction of the Hon'ble Supreme Court Order in W.P No (C) 657/1995.
2 The unit has valid consent and Hazardous | Yes waste authorization. Air &Water :AW-323366 Valid up to 30-06-2023 HWM No. 326667 Valid till 30-06- 2023 3 The source of water supply is own open | The Source of water is open well.
well and installed flow meter to record Flowmeter provided. the consumption of water from openwell. | KGWA NOC Obtained. The unit has not obtained NOC from the Karnataka Ground Water Authority (KGWA) for usage of Ground water for industry use. The average water consumption is 18 KLD.
Page 85 of 110 33ig The raw materials are stored properly in They have provided receivers to shed, where as they have provided avoid Handling of solvents. receivers for handling of solvents and We have provided primary and provided primary and secondary secondary condensers on reactors condensers on reactors for maximum for maximum recovery of solvents. recovery of solvents.
The Unit has installed OCEMs and connected to CPCB/KSPCB. The OCEMS is found working.
The unit has 20 KLD ETP, the low TDS e Strict operational controls are and High TDS effluent are combined developed while handling the treated with neutralization followed by Multiple Effect Evaporator (MEE) and effluents.
Page 86 of 110 34Agitated thin Film Drier (ATFD). Effluent is being neutralized The MEE Condensate is used as Boiler to 7.5 pH before feeding to feed. The analysis results of effluent samples reveals that, the MEE condensate MEE. is reported with high concentration of Proper care is been taken COD and acidic pH, which indicates that during process at the layer poor performance of MEE condenser and condensate generated is not suitable for separations steps to avoid recycling as cooling tower, make up high COD to effluent. water. Additionally, stripper is provided to remove the MSV Analytical Laboratories solvent traces to avoid high COD in treated effluent.
The condensate water is being analysed regularly by the NABL approved third party laboratory. We are obtaining recyclable quality.
The analysis report is attached for ready reference.
The unit has storage of large quantity of They are segregating different process residue, spent carbon and MEE categories of Hazardous salts about 7.5 Tons, the storage area is not having spillage collection pit existing Waste and storing in double HW storage area. The unit is maintaining layered bags separately on Page 87 of 110 35 inventory of HW and Inventory is found pallets in the dedicated displayed at storage area. The hazardous Hazardous Waste Storage residue drums and raw materials (Solvent drums) are stored in same shed; the same Area. shall be stored securely in designated e Hazardous waste is being hazardous waste storage area.
disposed to TSDF regularly as per Hazardous Waste handling rules.
e Leachate collection pit is provided in the hazardous waste area and photograph is enclosed.
The process area not provided with They have provided Spillage spillages collection pits.
collection pits in process area. Photographs enclosed.
Page 88 of 110 36The unit has provided rain water They have provided impervious percolation tank for all roof top and surface runoff water collection surface run off collection, the same need to be modified with the impervious tank tank to re-utilise storm water. of adequate capacity to reutilize the same. Since the surface run off is contaminated not advisable to percolate into ground water.
10 The unit uses coal as fuel for boiler and They have covered the Coal Ash ashes generated shall be properly shed three Sides to control fugitive handled. emission from coal ash handling.
Photographs Enclosed.
1 The process scrubber liquid shall be They have provided apermanent x directly taken to ETP (MEE) by installing | pipe line to pump scrubber liquid to permanent pipeline, to avoid spillages. ETP collection tank for further treatment. Photograph enclosed.
11 There is an existing open well in the plant | Industry is presently using the water premises, open well sample was collected from Open well.However this open Page 89 of 110 Page 90 of 110 40 JOINT INSPECTION REPORT Name of the Industry Inspected: Corvine Chemicals & Pharmaceuticals Ltd.
Name of the Inspecting Officers:
1. Shri S Madhusudhan Senior Environmental Officer, Zonal Office Kalburgi.
2. Shri Gopalkrishna B Sanatangi Environmental Officer KSPCB Bidar.
Reference: The Board direction issued vide memo dated: 05.04.2022 Date of Inspection 07.04.2022, 13.04.2022 and monitoring carried on 11.04.2022 Consent status Water Act 1974 Air Act 1981 Combined CFO No. AW-325340dt: 19.06.2021 Valid upto: 30.06.2026.
Products manufactured As per CFO.-- | Actual Manufactured (Quantity) (for the year 2021-22)
1. Sodium Azide 180 TPM 558.21495 MT/ Year
2. Trityl Chloride 80 TPM 341.017 MT/ Year
3. 5-Methy] Tetrazole 15 TPM 19.791 MT/ Year HWM Status Authorization No. 327230 dt: 30.09.2021 Valid upto: 30.06.2026 Details of products Manufactured Oty Intermediates SL. No. Product TPM Intermediates Quantity : ante _ sen | | Sodium Azide 180 -- = 2 Trity! Chloride 80 -- sesh 3 Ciprofloxacin HCL 30 --- = 4 BHT 15 --- a 5 5 Methyl Tetrazole 15 wt a 3.
6 5 Amino Tetrazole 15 --- |
a Dabigatran Etexilate 3.0 Stage-1 (Dabigatran 6.6
Mesylate |Ethyl Acetic Salt) os
Stage-2 (Dabigatran 3.0
oe Etexilate) --
8 Donepezil HCL 3.0) Stage- | (Dehydro 3.75
Denepezil)
Stage- 2 (Donepezil) 3.0
9 Pirfenidone 3.0 Stage- | (2- a7
Hydroxy 5-
| Methyl pyriding)
Page 91 of 110
41
10 Solifenacin 3:0) Stage-1 (S) -Ethy} 1- $3
Succcinate Phenyl-3,4-Dihydro
isoquinoline -2(1H)- ?)
carboxylate
11 Tamsulosin 3.0 'Stage- 33
Hydrochloride 1(Ethoxyphenoxy)
ethyl amino propyle
2|-methoxy benzene
sulfoamide) |
12 1H Tetrazole (1- HT) 2.0 --- ide
3 5-Benzyl Thio Th 2.0 = ian
Tetrazole (5- BTT)
14 4,5-Di Cyano Imidazole 2.0 --- Be:
(DCI)
15 Ethyl ThioTetrazole 2.0 --- a=
(ETT)
16 5-Phenyl 1 H-Tetrazole 2.0 --- ae
(5Ph T)
By-Products hi oa
S.No. Product Oty. TPM Byes Oty:
TPM
] Sodium Azide 180 Sodium Sulphate 245
HCI 115
2 Trityl Chloride 80 4
AICI; 320
Ammonium Acetate 15
3 Ciprofloxacin HCl 30
Piperzine 12
WATER POLLUTION CONTROL STATUS Source of water: Open well / Water supplier (tankers) during summer. a Quantity of water consumption as per Consent: 288 KLD Actual water consumed for different purposes:60-70 KLD iS Quantity of effluent generation from different sources as per CFO:
Sources of generation Quantity | Mode of treatment and disposal "Tr Domestic 10.0 KLD Sewage treatment plant. "
Process 27.62 KLD : |
Washings 2.0 KLD |
Boiler blow down 5.0 KLD MEE/ ATFD/ BTP& RO |
RO Rejects 2.0 KLD
"Tf any others ~ |70KLD
Page 92 of 110
42
DETAILS OF EFFLUENT TREATMENT PLANT
STP units - | No. Capacity : 20KLD (Domestic waste) MEE - | No, Capacity :30 KLD eanoge ATFD - | No. Capacity : 12 KLD Condensate treatment plant (BTP) -- | No. Capacity:40 KLD. RO Plant - | No.Capacity: 1.0 KL/hour AIR POLLUTION CONTROL STATUS SLNo. | Air Pollution source Air pollution control | Chimney | Monitoring equipment provided | height facility above ground level 1 Process emissions from Provided 4 Nos of 9 Mtr Provided GLR, Scrubbers to 16 Nos_ | 40Nos. portal No of GLRs- 16 Nos. GLR. Each Scrubber connected to 4 GLRs.
2 Boiler with capacity Mechanical 30 Mtr Provided
i) 3.0 TPH -1INo. Dust collector 2 Nos. portal
ii) 2.0 TPH -- 2Nos 3 D.G sets with capacity = --- | 6Mtr |: Provided |i) 500 KVA-2 Nos 2 Nos. portal 4 | MEE <-- = OCEMS | 3 ATFD o-- --- No Vents SOLID WASTE MANAGEMENT
1. HAZARDOUS WASTE :
SL.NO | SOURCE OF QUANTITY MODE OF | PRESENT GENERATION OF STORAGE STOCK IN GENERATION | AND THE DISPOSAL | STORAGE YARD | | Process residue --- -- sae | 2 Activated carbon 15-20 Kg/ day Stored in HW | 1.39 MT storage site, disposed to as 7 TSDF:
3 MEE salts - 200 -300 Kg/ Stored in HW | 11.20MT
day storage site,
disposed to
TSDF,
4 Discarded Containers | 15-20 Nos / Stored in HW | 13 Nos
month storage site,
Page 93 of 110
43
disposed to
Authorized
Recycler.
Used Oi] 120-150 Lt/ Stored in HW | Nil
| year storage site,
disposed to
Authorized
Recycler.
Spent Solvent 200-250 Kg/ day Stored in HW | 0.21 MT
storage site,
disposed to
Authorized
2. OTHERWASTE: hoo
SL.NO SOURCE OF QUANTITY
OF MODE OF |PRESENT
GENERATION GENERATION STORAGE STOCK IN THE
AND STORAGE
DISPOSAL YARD
Domestic
Office stationeries
Storedin
designated
E-Waste 22 3 Nos/ year area, disposed | Nil
to authorized
recycler.
Stored in
| Boiler ash 4 -6 Kg /day designated
120 Kg.
area, disposed
to recycler.
Stored in
Scraps Iron and Steel designated
IOMT/ Year 2MT
area, disposed
to recycler.
COMPLIANCE TO THE OBSERVATIONS OF THE JOINT COMMITTEE VISIT
DATED 27.11.2019
SI.No. Observations Compliance
The unit has displayed the consent and Displayed Consent and Hazardous waste|
H.W Authorization conditions at the Authorization conditions at the entrance of | entrance of the unit, as per the | the factory.
direction of Supreme Court order in W.P (C) 657/1995. The unit has valid Photograph of display board is enclosed as consent and H.W. Authorization. Annexure-1.
Page 94 of 110 44The source of water supply for Obtained NOC for the usage of industrial use is open well and has groundwater for industrial purpose from | installed flow meter for recording Karnataka Groundwater authority, water consumption. But, the unit has Bengaluru. not obtained NOC from the Karnataka Groundwater Authority (KGWA) for NOC obtained from KGWA is Enclosed as usage of groundwater for industrial Annexure-2. purpose.
Photograph of Flow meter provided for Open well enclosed as Annexure-3. The log book extract of water meter readings is | enclosed as Annexure-4. | The raw material are stored in closed The quantity of solvent used in al shed and having closed loop system manufacturing process is very less and no | | for solvent handling. But still some of manual handling of solvents is carryout | the solvent are handled in barrels and all the solvents are sucked by vacuum manually. pump. The photographs of vacuum solvent sucking system is enclosed as Annexure-5.
The process area is not provided Spillage collection pits are provided in spillage collection pit. process area. The Photographs of spillage| collection pit is enclosed as Annexure-6.
The unit has not provided designated They have constructed designated storage>|| place for the storage of by-product i.e. facility for storing Sodium Sulphate (by- | | Sodium Sulphate etc. product). The photograph is enclosed as | Annexure-7.
Acid and alkaline scrubbers are Dyke wall and collection pits ere provided as air pollution control provided in the scrubber area. The photos | equipment to all Glass Line Reactors enclosed as Annexure-8. (GLR's) to handle the process | emissions, But, the alkaline scrubbers | area is not provided with dyke or | | spillage collection pits to avoid aby soil contamination.
Used solvent drums / barrels are stored Used solvents drums are washed in a in an open area, the same need to be separate special washing area, Washing's shifted to the designated place after are collected into effluent collection tank washing for disposal to the recyclers. and then stored under closed condition in the Hazardous waste storage site. The photo graphs of discarded containers | a stored in designated area is enclosed as | Annexurre-9, Photo of Special (Equipment) washing area is enclosed as Annexure-10 Page 95 of 110 45 |Coal / briquettes are used as fuel in Boiler ash lumps & fine ash ts collected in } Boilers, the ash generated from the separate bags and stored in designated boilers, ash lumps & fine ash shall be area.
aa) stored separately in bags to avoid Photos are enclosed as Annexure-1 1. fugitive emission.
9 There are no dyke walls between the | Provided dyke wall between acid storage acid storage tanks, as per the | tanks. Photos are enclosed as Annexure- compatibility of acid. There is no |} 12. scrubber system provided to the acid storage tank (HCL) to handle the acid | Scrubber system is provided to HCl fumes during handling of acids. storage tanks. Photographs of Scrubber is | enclosed as Annexure-13. :
10 The unit has provided surface runoff | As per suggestion of technical person collection tank with outlet for] present surface runoff collection tank overflow. But the existing capacity of | (Capacity-30.00KL) is sufficient with collection tank provided is not] compared to plant area. Surface runoff adequate and same shall be increased | collection tank's outlet was closed. with a provision to reuse after | treatment. The collection tank outlet | Photographs of Surface runoff collection | shall be removed to avoid any outside | tank is enclosed as (Annexure-14), discharge. ag) 11 The unit has provided OCEMS system | They have provided MEE ~-- OCEMS | for the treated effluent, connected to | system for the treated effluent connected to | CPCB / SPCB and found operating. CPCB / SPCB and found operating.
photos of OCEMS camera enclosed ss (Annexure-15).
12 MEE condensate is reported with high i They have installed Biological treatment |! concentration of COD and alkaline plant and RO plant from which the | pH, which indicates the poor condensate of good quality, is obtained | performance of MEE _ condensate and being recycled. | generated is not suitable for recycling as cooling tower, make up water. photos of Aeration tank and RO plant| enclosed (Annexure-16).
ee = esl:
MONITORING:
1. The sample of condensate before BTP and after BTP is collected for analysis.
2. The sample of open well/tube well collected for analysis.
3. The sample of ambient air quality is conducted.
4. The emission from scrubber outlet is collected for testing acid mist concentration.
The above samples are submitted to KSPCB Laboratory for analysis purpose. The report is awaited.
Apart from the above, the following important observations were made:
a. There is no discharge/bypass of effluent to outside the premises. b. The said unit has adopted Zero Liquid discharge facility.Page 96 of 110 Page 97 of 110 Page 98 of 110 Page 99 of 110 Page 100 of 110 Page 101 of 110 Page 102 of 110 Page 103 of 110 Page 104 of 110 Page 105 of 110 Page 106 of 110 Page 107 of 110 Page 108 of 110 Page 109 of 110 Page 110 of 110